Date of Award
Bachelor of Science
Emma W. Goldman
Raymond N. Dominey
Rhenium (Re) is a group 7 heavy 5d transition metal in the same family as manganese (Mn) and technetium (Tc). Re-carbonyl complexes are known to be catalysts for many different kinds of reactions from C-C bond formation to reduction reactions like CO2 reduction (CO2RR)1,2. With this in mind, we have prepared a set of six Re-carbonyl complexes of 2,2′-pyridyl-1,6-naphthyridine (1,6- pynap) and 2,2′-pyridyl-1,8-naphthyridine (1,8-pynap), a redox non-innocent ligand containing a bpy moiety as well as an additional aryl nitrogen binding location at which another metal-ligand bond could form. We have synthesized these complexes as precursors to multi-metallic molecular catalysts and have studied their properties through UV-Vis and NMR spectroscopies.
Solomon, Benjamin F., "Synthesis and Characterization of Rhenium 2,2′-pyridylnaphthyridine Metal Complexes" (2023). Honors Theses. 1714.